Chemistry of fluoroalkyl cyanides
نویسندگان
چکیده
منابع مشابه
Detoxication of Aromatic Cyanides
The toxicity, physiologic effects, and antidotes are the points emphasized in the existing literature on the cyanides; Giacosa and Baumann alone have been interested in their fate in the body. Reports are unanimous that the aliphatic cyanides split off hydrocyanic acid, and that toxicity is directly proportional to the rate at which this splitting occurs, while an increase in the excretion of t...
متن کاملSome Physiological Actions of Cyanides
1. The physiological actions of HCN and its salts appear to be due (a) to the ease with which HCN molecules penetrate living cells and then ionizing, exert their influence by means of H ions and CN ions; (b) to the weakness of HCN as an acid, which permits at neutrality or at even slight alkalinity the presence of a considerable amount of free HCN molecules in the presence of their salts; (c) t...
متن کاملA generic route to fluoroalkyl-containing phosphanes.
The reaction of trimethylsilyl-containing phosphanes with perfluoroiodoalkanes provides a general and convenient route to perfluoroalkyl-containing phosphanes.
متن کاملThe activation of alkyl cyanides using a rhodiumtrispyrazolylborate complex.
The photochemical reaction of Tp'Rh(L)(eta2-PhN=L) [Tp' = tris-(3,5-dimethyl pyrazolyl)borate, L = CNCH(2)CMe(3)] to form the coordinatively unsaturated reactive fragment, [Tp'Rh(L)], in the presence of alkylnitriles has been studied. The [Tp'Rh(L)] complex has been shown to selectively activate the primary C H terminus of acetonitrile, propionitrile, butyronitrile, and valeronitrile. The resul...
متن کاملFacile synthesis of hydrophobic fluoroalkyl functionalized silsesquioxane nanostructures.
New fluorinated polyhedral oligomeric silsesquioxane (F-POSS) structures possessing a high degree of hydrophobicity have been prepared via a facile corner-capping methodology.
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2020
ISSN: 1551-7012
DOI: 10.24820/ark.5550190.p011.339